Histone Lysine acetylationAcetylation (ac) occurs exclusively on lysine residues of histone peptides and is widely studied. It is catalysed by a special category of enzymes called the 'lysine acetyltrasferases'. The acetyl-CoA acts as the acetyl group donor. Acetylation causes neutralisation of the positively charged lysine residues. Hence, this modification hampers the histone-DNA interaction. Acetylation increases the weight of histone peptide by ~42 Da per acetyl moiety.
Histone acetylation is predominantly associated with transcriptional activation. They are also important for normal progression of the cell cycle. Certain specific residues are acetylated during DNA damage and this helps in efficient DNA repair. Acetylation helps in subsequent recruitment and activity of various chromatin remodelling machinery as well as modification of other residues on the same histones or the neighbouring ones. Loss of H4K16 acetylation is considered to be a hallmark of cancer.
Download table as ExcelSites of histone Lysine acetylation Site of modification | Writers | Erasers |
H1K25ac |
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NAD-dependent deacetylase sirtuin-1 |
H2AK5ac |
Histone acetyltransferase KAT5,
Histone acetyltransferase type B catalytic subunit | |
H2AK9ac | | |
H2BK120ac | | |
H2BK12ac | | |
H2BK15ac | | |
H2BK16ac | | |
H2BK20ac | | |
H2BK46ac | | |
H2BK5ac | | |
H3K14ac |
Bifunctional protein NCOAT,
Circadian locomoter output cycles protein kaput,
General transcription factor 3C polypeptide 4,
Histone acetyltransferase KAT2A,
Histone acetyltransferase MYST3 | |
H3K18ac |
CREB-binding protein,
Elongator complex protein 3,
Histone acetyltransferase p300 | |
H3K23ac | | |
H3K27ac |
CREB-binding protein,
Histone acetyltransferase p300 | |
H3K36ac | | |
H3K4ac | |
Histone deacetylase 3 |
H3K56ac |
CREB-binding protein,
Histone acetyltransferase p300 |
Histone deacetylase 1,
NAD-dependent deacetylase sirtuin-2,
NAD-dependent deacetylase sirtuin-3, mitochondrial,
NAD-dependent deacetylase sirtuin-6 |
H3K9ac |
Elongator complex protein 3,
Histone acetyltransferase KAT2A |
NAD-dependent deacetylase sirtuin-1,
NAD-dependent deacetylase sirtuin-6 |
H4K12ac |
CREB-binding protein,
Histone acetyltransferase KAT2A,
Histone acetyltransferase KAT5,
Histone acetyltransferase MYST2,
Histone acetyltransferase p300,
Histone acetyltransferase type B catalytic subunit | |
H4K16ac |
CREB-binding protein,
Histone acetyltransferase KAT2A,
Histone acetyltransferase p300,
Probable histone acetyltransferase MYST1 |
NAD-dependent deacetylase sirtuin-1,
NAD-dependent deacetylase sirtuin-2 |
H4K5ac |
CREB-binding protein,
Histone acetyltransferase KAT2A,
Histone acetyltransferase KAT5,
Histone acetyltransferase MYST2,
Histone acetyltransferase p300,
Histone acetyltransferase type B catalytic subunit | |
H4K8ac |
Bifunctional protein NCOAT,
CREB-binding protein,
Histone acetyltransferase KAT2A,
Histone acetyltransferase KAT5,
Histone acetyltransferase MYST2,
Histone acetyltransferase p300 | |
H4K91ac |
Histone acetyltransferase KAT2A | |